导 师 简 介
石楼，男，昆明学院硕士生导师，云南省“兴滇英才支持计划”青年人才。
主持省部级项目3项，发表SCI论文20多篇，申请授权国家发明专利1件。
主要研究领域：
有机合成方法学，主要包括光、电催化绿色有机合成，过渡金属催化等。
近五年代表性项目：
[1] 云南省科技厅，基础研究计划-青年项目，202401AU070022,电诱导富电子烯烃区域选择性碳/杂环合成，2024-03至2027-02，5万元，在研，主持
[2] 云南省科技厅，地方本科高校基础研究联合专项-面上项目，202301BA070001-016，吲哚自由基参与的电化学氧化/环化反应，2023-11至2026-10，10万元，在研，主持
[3] 云南省教育厅，教师项目，2023J0838，电化学诱导合成1,3-二氢吡咯-2-酮研究，2023-03至2025-02，2万元，已结题，主持
近五年代表性论文（按发表年倒序排列）：
17. Fu T.; Ji X.; Lv S.; He R.; Shi L.;* Shi W.-M.;* Liang D.,* Light-Induced 1,4-Difunctionalization of Doubly Activated Cyclopropanes for the Synthesis of 3-Ethylacylamino-2-quinolones. Organic Letters 2025, 27, 7494−7500.
16. He, R.; Zhang, Z.; Zhou, Y.; Zeng, L.; Shi, L.;* Liang, D.,* t-BuOLi-promoted Knoevenagel condensation: An efficient approach for synthesizing Arylid-BOX. Tetrahedron Letters 2025, 168, 155706.
15. Ma, Y.; Yu, P.; Qin, R.; He, R.; Zeng, L.; Shi, L.;* Sun, S.;* Liang, D.,* Electrophotocatalytic Thiocyanation and Sulfonylation Cyclization of Unactivated Alkenes. The Journal of Organic Chemistry 2025, 90, 598−613.
14. Zi, J.; Tang, H.; Wang, D.; Li, M.; Zhou, Y.; Lv, S.; Liang, D.,* Shi, L.,* Electrochemically enabled dearomative [2 + 2] cycloadditions of indoles with alkynes to access cyclobutene-fused indolines. Green Chemistry 2024, 26, 10397–10403.
13. Zhang, X.; Li, W.; Zhou, Y.; Lv, S.; Xu, L.; Shi, L.;* Li, Y.;* Liang, D.,* Electrochemical 1,5-chlorosulfonylation and 1,5-hydrosulfonylation of vinylcyclopropanes. Organic Chemistry Frontiers 2024, 11, 5564–5572.
12. Yang, Z.-X.; Ding, L.-C.; Yang, G.-H.; Wang, D.; Shi, L.;* Li, Y.; Liang, D.,* Electrochemical Sulfonylation/Cyclization of N-Alkenylacrylamides with Sodium Sulfinates or Sulfonyl Hydrazides. The Journal of Organic Chemistry 2024, 89, 10660−10677.
11. Yang, X.; Shi, L.;* Qin, R.; Tao, M.; Feng, Q.; Chang, X.-Y.; Chang, Q.; Liang, D.,* Photoredox/nickel dual-catalysis-enabled synthesis of N-heterocycles from alkyl chlorides and alkenes. Molecular Catalysis 2024, 553, 113806.
10. Wang, D.; Zeng, L.; Shi, J.; Gao, S.; Shi, L.;* Sun, S.;* Liang, D.,* Electrophotocatalysis Versus Indirect Electrolysis: Electrochemical Selenocyclization of 3‐Aza‐1,5‐dienes Facilitated by Energy Transfer, Direct Photolysis or N‐Hydroxyphthalimide. Chemistry–A European Journal 2024, 30, e202400280.
9. Tao, M.; Feng, Q.; Gong, K.; Yang, X.; Shi, L.;* Chang, Q.;* Liang, D.,* Photoredox streamlines electrocatalysis: photoelectrosynthesis of polycyclic pyrimidin-4-ones through carbocyclization of unactivated alkenes with malonates. Green Chemistry 2024, 26, 4199−4208.
8. Shi, L.;* Xu, P.; Ma, Y.; Dong, Y.; Li, Y.;* Liang, D.,* Copper‐Promoted Oxidative Amide‐Assisted Radical Selenylation of Anilides and N‐Arylsulfonamides with Diselenides. Asian Journal of Organic Chemistry 2024, 13, e202400043.
7. Ji, X.; He, R.; Shi, L.;* Sun, S.;* Liang, D.,* Synthesis of Diverse 4‐Pyrroli-2-ones by Electrochemically Induced Dehydrogenative Regioselective Cyclization of 3‐Aza‐1,5‐dienes and 1,3‐Dicarbonyl Compounds. European Journal of Organic Chemistry 2024, 27, e202301246.
6. Yang, R.; Chen, D.; Lin, S.; Yang, X.; Shi, L.;* Chang, Q.;* Liang, D.,* Photoinduced Regioselective Perfluoroalkylation/Cyclization Cascade of 3‐Aza‐1,5‐Dienes: Access to Pentasubstituted 3‐Perfluoroalkyl‐1,3‐Dihydropyrrol‐2‐Ones. European Journal of Organic Chemistry 2023, 26, e202300528.
5. Yang, R.; Chen, D.; Lin, S.; Yang, X.; Hu, X.; Gao, S.; Shi, L.;* Liang, D.,* Cation-π-interaction-facilitated, self-photocatalyzed and regioselective perfluoroalkylation of 3-aza-1,5-dienes. Molecular Catalysis 2023, 547, 113360.
4. Wang, S.; Shi, L.; Chen, X. Y.; Shu, W., Catalyst-Controlled Regiodivergent and Enantioselective Formal Hydroamination of N,N-Disubstituted Acrylamides to α-Tertiary-α-Aminolactam and β-Aminoamide Derivatives. Angewandte Chemie International Edition 2023, 62, e202303795.
3. Chen, D.; Yang, X.; Wang, D.; Li, Y.; Shi, L.;* Liang, D.,* Electrophotocatalytic tri- or difluoromethylative cyclization of alkenes. Organic Chemistry Frontiers 2023, 10, 2482–2490.
2. He, J.-Q.; Yang, Z.-X.; Zhou, X.-L.; Li, Y.; Gao, S.; Shi, L.;* Liang, D.,* Exploring the regioselectivity of the cyanoalkylation of 3-aza-1,5-dienes: photoinduced synthesis of 3-cyanoalkyl-4-pyrrolin-2-ones. Organic Chemistry Frontiers 2022, 9, 4575–4582.
1. Shi, L.; Xing, L. L.; Hu, W. B.; Shu, W., Regio- and Enantioselective Ni-Catalyzed Formal Hydroalkylation, Hydrobenzylation, and Hydropropargylation of Acrylamides to α-Tertiary Amides. Angewandte Chemie International Edition 2021, 60, 1599−1604.
申请/授权国家专利：
[1] 潘玲；刘群；石楼；一种4-氨基喹啉化合物及其制备方法，2019-06-25，中国，201611025139.7
联系方式：
664637226@qq.com
